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Compound reference

Hydrogen fluoride

HF

FH
Geometry
linear
Bond angle
180°
Elements:HF

The chemistry

Fluorine grabs hydrogen with one bond - and hides three lone pairs. The greediest atom you'll meet.

Remember it as…

One bond, three lone pairs on F. Most electronegative atom on the table - H–F is the most polar simple bond there is.

Common mix-up

HF is a WEAK acid in water, not a strong one. The H–F bond is so strong (and F⁻ holds H⁺ so tightly) that the dissociation is incomplete - counterintuitive given fluorine's electronegativity.

Where the name comes from

Fluorine from Latin fluere (to flow) - early metallurgists used fluorspar (CaF₂) as a flux to make ores melt and flow.

Where you meet it

Etches glass; used to make non-stick coatings, refrigerants, and pharmaceuticals; vapor is corrosive enough to dissolve cell membranes on contact.

PubChem facts

IUPAC name
fluorane
Molecular weight
20.0064 g/mol

Also known as: hydrofluoric acid (the water solution), hydrofluoride

Handling note

Intensely corrosive and toxic; in water (as hydrofluoric acid) it even attacks glass and penetrates skin to the bone.

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BondingMolecular geometry

Chemical data from PubChem (NIH/NCBI)